St. James’ Church is located on US Rt. 3 in the middle of Montross, Virginia, across the street from the Montross Town Hall, near the US Post Office. Parking lot, cemetery, office, and handicap access to Parish Hall and Church is off of Rectory Road across from the Fire Department (off of Rt. 3 turn at Rite-Aid Drug Store onto Rectory Road; go 1/2 block, turn left at black-top driveway to paved parking lot; handicap parking spaces are available).

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St. James’ Church is in the middle of historic Westmoreland County.  Wakefield, the birthplace of George Washington, and Stratford Hall, the birthplace of Robert E. Lee, are both nearby. Also nearby is Westmoreland State Park, Colonial Beach, and other places of interest.